Making Wood Last Forever With Acetylation | August 6, 2012 Issue - Vol. 90 Issue 32 | Chemical & Engineering News
Volume 90 Issue 32 | pp. 22-23
Issue Date: August 6, 2012

Making Wood Last Forever With Acetylation

Companies like Eastman Chemical and Accsys are marketing chemically modified, long-lasting wood
Department: Business
News Channels: Materials SCENE
Keywords: acetylated wood, cellulose acetate, acetic acid, acetic anhydride, lumber, wood, materials
Eastman is targeting outdoor furniture and decking with its Perennial Wood brand of acetylated wood.
Credit: Eastman
Eastman is targeting outdoor furniture and decking with its Perennial Wood brand of acetylated wood.
Credit: Eastman

No building material is as familiar as wood. Most everyone on Earth has walked on it or been sheltered by it. Even the least handy among us has had occasion to form it, cut it, or drive a nail through it. The shortcomings of wood are also familiar. Who hasn’t treaded gingerly on rotting planks or struggled with a window swelled by dampness?

Acetylation, a chemical reaction first employed more than a century ago, may solve these problems and make wood a building material of the future as well as of the past. After many attempts over the years to commercialize acetylated wood, a host of firms believe the material’s time has come.

Unlike pressure treatment, in which preservatives such as ammoniacal copper quaternary compounds are infused into wood, acetylation chemically modifies wood. In the process, acetic anhydride reacts with the hydroxyl groups on large molecules such as lignin and hemicellulose in the plant cell wall. The reaction replaces hydroxyl groups with acetyl groups and yields acetic acid as a by-product.

It’s the same chemistry employed since the early part of the last century for making cellulose acetate—acetylated wood pulp—for photographic film, wedding dress fabric, cigarette filters, and playing cards.

Several firms are ramping up output of acetylated wood and are seeding the market with product. Eastman Chemical, one of the world’s major cellulose acetate makers, is acetylating wood at its Kingsport, Tenn., chemical complex. The lumber is being sold under the Perennial Wood brand name at 50 Lowe’s stores in New England. Accsys Technologies develops acetylation technology, which it is licensing to third parties, and also acetylates wood in Arnhem, the Netherlands.

These companies are betting that consumers are willing to pay for the improved wood properties—namely better dimensional stability and decay resistance.

Roger Rowell, professor emeritus of biological systems engineering at the University of Wisconsin, Madison, explains that newly harvested “green” wood will lose about 10% of its volume when it is dried before being cut into lumber. Introducing acetyl groups stretches out the wood’s cell walls again, locking the wood back into its original volume. “It is about as big as it can get,” he says. “Water doesn’t swell it.”

Acetylated wood has the strength of regular wood that is very dry, Rowell says. For every 1% gain in moisture, wood loses about 5% of its modulus of rupture, a measurement of how a material bears a large load. “Is acetylated wood stronger?” he asks. “Yes, by quite a bit, because it is drier.” Similarly, acetylated wood resists termites partially because it is harder than unmodified wood.

Acetylated wood isn’t hard to work with, its backers say. “All the construction techniques that you can use with wood, you can use on acetylated wood,” says Jimmy Dickerson, Eastman’s technology manager for acetylated wood.

However, Eastman recommends using stainless steel fasteners with acetylated wood because residual acetic acid would corrode regular steel. The acetic acid can also make the wood smell like vinegar, something that acetylated wood producers can reduce by wicking out excess acid and applying a finish to the wood.

There are two main schools of thought as to why acetylated wood resists decay. One is that acetylation changes the conformation of the substrate that fungi are trying to eat. The fungal enzymes that break down the wood don’t recognize it as food.

Rowell is a proponent of another theory based on research he did in Sweden 20 years ago. Again, dryness is the key. “Acetylation reduces moisture in the cell wall to the point where there just isn’t enough to support fungal degradation,” he says. “In other words, in order to hydrolyze a glycosidic bond, you have to have a molecule of water. And if you don’t have water at the glycosidic bond, hydrolysis can’t take place.” Glycosidic bonds link carbohydrate molecules in polysaccharides such as cellulose.

If acetylation imparts such benefits, why didn’t it take off decades ago? Rowell notes that patents covering acetylated wood do date back to the 1930s, but the handful of companies that subsequently attempted to introduce it had little luck. For example, Koppers tried launching a product in the 1960s. Japan’s Daiken introduced acetylated wood flooring in the 1980s. And firms involved in acetyl chemistry such as Eastman and BP have long dabbled in the technology.

Observers cite technical and economic reasons for why acetylation hasn’t been viable until now. Although the process involves chemistry similar to that used to make cellulose acetate, there are subtleties to using whole wood, Eastman’s Dickerson notes.

“One of the beautiful things about wood is its uniqueness. Every piece of wood is different,” Dickerson says. “That same character is a nightmare for a chemist.” Additionally, producing cellulose acetate involves acetylating a well-dispersed fiber, he says. A block of wood, on the other hand, has much less surface area. For aceytlation to be beneficial, the reaction needs to penetrate deep into the wood.

Another difference, Rowell points out, is that cellulose acetate is made with a catalyst such as sulfuric acid. But acetylating cellulose in wood is undesirable because cellulose is the source of the wood’s strength. In order to relegate the reaction to the lignin and hemicellulose, commercial wood acetylation processes tend not to use catalysts, Rowell says.

Acetylated wood also isn’t cheap. At Lowe’s, a 16-foot board of premium pressure-treated decking goes for $14.57. The same board of Trex plastic composite decking can cost up to $44.97. A Perennial Wood board will set the consumer back $51.74.

Eastman’s Dickerson says consumers are becoming used to paying more for materials such as composite lumber because of their durability. “The synthetic materials that are out there have largely proved a price point, particularly in decking,” he says.

Paul Clegg, chief executive officer of Accsys, says alternative materials have raised the bar in other applications as well. For example, wood was once the dominant material for building windows. Today in the U.K., some 90% of the windows installed in new structures are made of aluminum or polyvinyl chloride, which don’t swell as wood does. “The PVC and aluminum industries have done a fantastic job in raising the level of expectation,” he notes.

Companies are commercializing this process to make wood endure.
Companies are commercializing this process to make wood endure.

Yet architects and consumers increasingly want renewable construction materials, Clegg points out. They are also shying away from using materials from carbon-intensive industries, such as PVC and aluminum.

Eastman and Accsys are approaching the acetylated wood market differently. Eastman is initially focusing on decking materials. Dickerson says the company is also gaining traction in outdoor furniture and porch flooring markets.

Rather than license the technology to a wood company, Eastman has decided to manufacture and market acetylated lumber itself. Dickerson says it is easier to bring wood onto a chemical site than it would be to duplicate the chemical infrastructure in a wood processing plant.

Since 2007, Accsys has run a plant in Arnhem, where 12.5-meter-long tube-shaped pressurized reactors can create up to 40,000 m3 of its Accoya acetylated wood per year. But the company’s long-term business model is to license its technology to third parties.

Last month it agreed to license the technology to Solvay’s Rhodia Acetow unit. By the end of 2014, Solvay expects to have built a 63,000-m3 Accoya plant, likely in Freiburg, Germany, where it already makes cellulose acetate. Accsys is also forming a joint venture with chemical maker Ineos to further develop and license its recently commercialized Tricoya technology for making boards from acetylated wood chips.

Although Accsys, like Eastman, is looking at decking, Clegg says windows, doors, and cladding are higher priority applications, largely because raw materials are a small part of the cost of such products. “For a window, wood is 15% of the cost, but it is 90% of the performance,” he says.

Clegg believes that consumers will eventually pay for the performance, but he also recognizes that the construction market is conservative. “The wood industry is not the semiconductor industry,” he remarks. “We don’t go from invention to obsolescence in 18 months.”

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John Royce  (January 9, 2013 3:14 PM)
For many who have great concern for the loss of the architectural integrity of our historic homes and buildings, especially concerning windows , doors and unique trimming, this product offers incredible hope for the future as an alternative to PVC products. While PVC is stable with changes in moisture levels, its propensity for expansion and contraction with temperature changes remains an issue, stressing window seals, for instance, over time to failure. Since wood is naturally stable with temperature swings, making it stable in changing moisture conditions suggests an ideal product for doors, windows, trim and decking; anything that is exposed to weather. I, for one, am very excited about the implications of this product!
Gary Frase  (February 18, 2013 8:33 AM)
What happens with acetylated wood in the waste stream? How will off-cuts and saw dust react in a compost pile for instance? Will it remian inert or will it degrade into what? Thanks, Gary Frase
d sanders  (May 1, 2013 10:56 AM)
What is the effect on fire behavior? Nitro-cellulose films used in the 20's were very flammable. Is this product similar? Is this intended for finish and trim use, not wall construction[U.L. rated systems].
Edward Pratt  (July 2, 2013 11:57 AM)
I noticed the comments / questions from Gary Frase and D Sanders. Acetylated wood is preferably re-cycled rather than disposed of as it can be re-used as solid wood or converted into a engineered wood product, such as MDF, if ground into fibres. It is definitely quite inert, but unless every free hydroxyl is capped there will be very gradual degradation (but it could - should, if acetylated to a level that is suitable for ground contact - last more than a hundred years). Worst case, unlike preserved wood, it can be burnt, which relates to D Sanders' question.

The material does have added energy and is slightly drier than unmodified wood. Unlike nitro-cellulose, though, its flammability is not greatly changed. Accsys Technologies has published the results of the independent testing which it commissioned - see

Being familiar with much of the research and with the tests that Accsys uses to quality control its acetylated wood (Accoya) production, I now have lots of acetylated (Accoya) things in / around my home: windows, doors, garden furniture, a retaining wall, fascia, trim board, garden steps, porch, decking, kitchen, bathroom and utility room flooring (which have suffered some floods) and a conservatory floor (which was placed on still-wet concrete...), plus an Accoya wood shed and, more recently,a Tricoya (acetylated MDF) outdoor table tennis table, sand box, planters, and soon siding... You can check with me (but not in 100 years) and I'll let you know how it's all looking (the windows look completely brand new 3 years on and shouldn't need painting for another 10 years).
Houston Pitts  (April 12, 2014 9:01 PM)
Does the Brand named pressure treated wood CHOICE sold by Lowes cause damage to aluminum when used on boat trailers for pontoon boat slides? The aluminum pontoons on pontoon boats can touch the slides.
Raj Sentoo  (April 29, 2015 3:41 AM)
with regards to acetylated wood, does the retention and penetration differ to that of CCA (chromate copper arsenate) or is it a totally different process altogether?
Thank You, Raj Sentoo
JoeM  (June 18, 2015 8:08 AM)
Sorry. But the presumption that people will pay alot more for acetylated wood over treated is naive. They won't. Because there are many extra treatment options out there that keep the cost of dimensional or treated far cheaper than this new stuff. Same reason why companies failed before. Too much overhead.
Hisham  (September 29, 2015 10:09 PM)
How to reduce the cost of acetylated wood. Acetic acid need to be separate with acetic anhydride. Can we change to butryric anhydride which no by product of acetic acid and the cost of separation is zero
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