Volume 93 Issue 33 | p. 37 | What's That Stuff?
Issue Date: August 24, 2015

What's that stuff? Nitro Cold Brew

Researchers ponder how pushing nitrogen into specially brewed coffee imparts a smooth, creamy flavor
Department: Science & Technology | Collection: Entrepreneurs
News Channels: Analytical SCENE, Organic SCENE
Keywords: coffee, cold brew, nitro cold brew, food science
Many coffee drinkers find nitro coffee (right) creamier and mellower than its traditional counterpart.
Credit: Jessica Morrison/C&EN
Shot glasses with coffee.
Many coffee drinkers find nitro coffee (right) creamier and mellower than its traditional counterpart.
Credit: Jessica Morrison/C&EN

Before Nate Armbrust was even working as a food scientist at Portland, Ore.-based Stumptown Coffee Roasters, he was daydreaming about how to push bubbles into a cold cup of coffee. Armbrust first tried carbonating coffee, but he quickly realized it was a terrible idea. “Coffee just doesn’t take acid the way juice or teas can,” he says. “When the CO2 becomes carbonic acid in solution, it just destroys the flavor.”

Then he started thinking about his home-brewing days and the appeal of Guinness poured fresh from the tap. That beverage is blended with nitrogen gas, which creates small bubbles that help stabilize a creamy head. Looking to replicate that creaminess with coffee, Armbrust struck upon the idea of pushing nitrogen gas into his cold coffee.

When he started working at Stumptown in early 2013, figuring out how to get the right amount of nitrogen into cold brew became a secret side project. After a month or so of playing with various times and pressures, he figured out the right balance of mouthfeel and flavor. With no small amount of trepidation, Armbrust took his concoction to colleagues. Thus was born Stumptown’s nitro cold brew. In June 2013, the hipster coffee gourmands put it on tap at their Portland café.

Stumptown’s coffee was one of the first nitro cold brews appearing at cafés around the country. Coffee lovers tout its frothy, creamy goodness, and Armbrust fields frequent calls from baristas interested in adding the product to their menu.

Nitro cold brew is made by percolating nitrogen gas through coffee that has either been brewed hot and then chilled or coffee that has been brewed in cold water. The coffee is often stored under pressure in a keg then poured straight from the tap. Just like Guinness, the foamy head comes from dissolved nitrogen bubbles. Nitro brew fans also claim that this foam helps the coffee retain a special flavor and aroma.

So what makes nitro cold brew taste so special? Researchers are only beginning to ponder this question. Certainly at the base of any good nitro cold brew is simply good coffee. The deliciousness of your cup of coffee—cold or hot—relies on a dizzying array of factors. From the bean you choose, to how you roast and grind it, to the intricacies of your brewing method, small changes have big impacts on the flavor molecules that end up in the coffee.

As a hot coffee cools, the flavor components undergo rapid changes in the headspace of your cup, notes Heather Smyth, a food science researcher at the University of Queensland, in Australia. Within the first few minutes of a hot brew, flavor components are actually changing, Smyth says. “Certain components are lost, while others are formed. Citrus notes disappear, while chocolate and black-currant notes become apparent as the coffee cools.”

Cold brewing, or allowing coffee grounds to steep overnight in cold or room-temperature water, should imbue a more constant flavor and aroma profile than that of hot-brew coffee because those molecules aren’t lost to steam, she explains.

Whether cold brewing does actually change composition of the flavor molecules dissolved in coffee, however, is not known. Armbrust notes that most coffee components are soluble in water, and allowing grounds to steep overnight should in theory allow just as many flavor molecules to be extracted in a cold brew. But no research has been published to establish exactly how cold brewing affects the molecular makeup, and thus the taste, of coffee.

Cold-brew lovers often cite its lower acidity as part of its appeal. But that lack of acidity is more about perception than pH, Armbrust believes. Chocolate and bright fruit flavors are the most prominent in cold brew, which tends to make it seem sweeter than hot-brewed coffee, he adds.

The beverage’s temperature is probably also altering the perception of its flavor. “Flavor is multisensory, and the temperature of coffee affects how you perceive it,” says Matthew Hartings, who teaches food chemistry at American University.

At Compass Coffee in Washington, D.C., where Hartings sampled a nitro-infused batch, the owners brew hot coffee with filtered water and cool it over ice before adding nitrogen under pressure. Michael Haft, co-owner of Compass Coffee, says anecdotal evidence suggests that the nitrogen is extending the life of the coffee.

As coffee ages in the pot, oxidation swiftly breaks down the originally robust flavor molecules, which is why good shops brew in small batches or toss out unsold quantities after 30 minutes, Haft says.

The nitrogen that Haft and co-owner Harrison Suarez bubble through their beloved brew is likely making the coffee more stable by pushing oxygen out of the liquid, Hartings says.

At Compass, Hartings was eager to see if the process also affects the pH of the coffee. If enough dissolved carbon dioxide is also pushed out by the nitrogen, the coffee should become less acidic, and therefore sweeter. He whipped out a pack of pH indicator strips to test his theory, but there was no noticeable difference.

“We definitely don’t have it all figured out,” Suarez says. Chemists, your coffee analysis help is needed.

Chemical & Engineering News
ISSN 0009-2347
Copyright © American Chemical Society
Cruser Rowland (Wed Aug 26 16:28:32 EDT 2015)
Nice article, thank you.
Grayson Fox (Thu Sep 03 20:02:33 EDT 2015)
I just found out about this from a local cafe in the SF Bay Area that was using Stumptown beans. It's really good. I would love to find out how cold-brewing affects the make-up of coffee, and what role nitrogen plays aside from mouth-feel.
Dave T (Tue Dec 29 12:45:44 EST 2015)
Is coffee sweetened or made creamy by nitrogen? Or is nitrogen masking or enhancing taste receptors and fooling us by changing the mechanics of taste? Also any thoughts on if nitrogen is a caffeine accelerant?
Matt Hartings (Mon Jan 04 18:41:22 EST 2016)
Hi Dave,
The version that I had at Compass was not sweetened or creamy. In the above picture, the coffee on the right had come from a nearly empty keg of coffee, so there was a higher concentration of N2 in the liquid. The coffee does not maintain its foam. I suppose that it could with the addition of some protein or other emulsifying agent. Also, the nitro coffee was not sweeter (as I thought it would be). The nitro brew actually lost a lot of the sweet/tangy/fruity notes that are present in Compass's regular iced coffee. (They make it by brewing with hot water which drips onto a container of ice.) So, their nitro coffee accentuated more of the "roasty" qualities of the bean. I am not sure how the Stumptown version (or other versions) differ from this. Seems that you can probably highlight different flavors/textures with different preps.
Jay T (Wed Jun 08 17:54:41 EDT 2016)
The nitrogen blanket within the pressurized container will displace O2, providing a non-oxidative environment. This may also have an effect on some of the more delicate flavors of the product.
Kenny B (Fri Jul 29 13:49:28 EDT 2016)
Out of curiosity, what would the water composition do to the extraction of flavor compounds in the coffee? I know that with brewing beer, making wine, and spirits, the water will effect the overall flavor of the final product. In beer, tannin can be extracted from grain husk if the pH of the mash is higher than 7.5. I'm assuming the same would apply to coffee. I would like to start of with RO water, build the water to a certain profile, and then cold brew the coffee. Anyone have any ideas or input? Thanks!
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