Advertisement

If you have an ACS member number, please enter it here so we can link this account to your membership. (optional)

ACS values your privacy. By submitting your information, you are gaining access to C&EN and subscribing to our weekly newsletter. We use the information you provide to make your reading experience better, and we will never sell your data to third party members.

ENJOY UNLIMITED ACCES TO C&EN

Materials

Two-faced fabric separates oil from emulsions

Cotton coated with cleverly designed polymer could find use cleaning up oil spills

by Bethany Halford
November 14, 2016 | A version of this story appeared in Volume 94, Issue 45

A new polymer-coated fabric could make it easier to separate troublesome emulsions, such as those that can occur during industrial-scale syntheses of organic chemicals or when oil is accidentally released into waterways. The material, developed by Guojun Liu, Zijie Wang, and Shuaishuai Huang of Queen’s University, in Ontario, is known as a Janus fabric because, like its namesake Roman god with two faces, it has two sides, each with a different property—one hydrophilic and one hydrophobic. The new Janus fabric is made by coating cotton with a block copolymer containing hydrophobic poly(dimethylsiloxane), known as PDMS, along with hydrophilic poly(N,N-dimethylaminoethyl methacrylate), known as PDMAEMA (Angew. Chem. Int. Ed. 2016, DOI: 10.1002/anie.201607581). In air, PDMS orients to the surface of the fabric. But when the fabric is exposed to an emulsion, the material acquires its Janus nature, with the PDMAEMA portion of the polymer migrating toward the emulsion and the PDMS moving to the opposite side of the fabric. Oil droplets from the emulsion start aggregating in the presence of the PDMAEMA and then move to the hydrophobic PDMS side. As such, the fabric serves two functions: It de-emulsifies and separates the oil.

Speedy Demulsifier
Oil and water: Hexadecane is moved into the chamber on the left from a dyed emulsion of hexadecane in water, thanks to separation by a new Janus fabric.
Credit: Angew. Chem. Int. Ed.
A dyed emulsion of hexadecane in water is de-emulsified using a Janus fabric.
Credit: Angew. Chem. Int. Ed.
A dyed emulsion of hexadecane in water (cloudy liquid) is exposed to a Janus fabric to selectively remove the hexadecane (clear liquid).

Article:

This article has been sent to the following recipient:

0 /1 FREE ARTICLES LEFT THIS MONTH Remaining
Chemistry matters. Join us to get the news you need.