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Web Date: January 8, 2014

Engineering Titanium Dioxide To Respond To Visible Light

Photocatalysis: Gently depositing nitrogen atoms on the surface of TiO2 makes the material active across a broader range of wavelengths of light
Department: Science & Technology
News Channels: Materials SCENE, Nano SCENE
Keywords: photocatalyst, photovoltaics, titanium dioxide, band gap

Many scientists view titanium dioxide as an attractive, low-cost photocatalyst for a variety of applications, including water purification, water splitting, and solar power. But there is one snag: The material catalyzes reactions only in response to ultraviolet light. Now, researchers in Singapore have found a way to dope TiO2 with nitrogen so that it responds to visible light, drastically increasing its activity in sunlight (J. Phys. Chem. C 2013, DOI: 10.1021/jp408798f).

A material’s photoactivity depends in part on its band gap, the energy needed to kick electrons from a nonconductive state to a conductive one. TiO2 has a band gap of 3 eV, which corresponds to energies of photons in the UV range. Doping TiO2 with nitrogen lowers the band gap below 2 eV, making the material photoactive with visible light. However, up to now, the doping methods used, such as magnetron sputtering and high-energy ion bombardment, have created defects in the bulk TiO2, which reduced the photocatalytic efficiency of the material.

A team of researchers from the Institute of Materials Research & Engineering (IMRE) and the National University of Singapore used a different source of nitrogen atoms that sent low-speed beams of atoms at the TiO2. Because these nitrogen atoms did not penetrate beyond the TiO2 surface, the researchers could replace the top layer of the material with nitrogen and create a defect-free surface, says Junguang Tao, a physicist at IMRE.

The team measured the photocatalytic activity of TiO2 samples with and without a nitrogen-doped surface. The doped TiO2 showed photoactivity when illuminated with visible light, unlike the undoped TiO2. What’s more, the surface-doped TiO2 showed greatly enhanced photoactivity under UV illumination, unlike TiO2 doped using previous methods.

Chemical & Engineering News
ISSN 0009-2347
Copyright © American Chemical Society
M. Reda /CanadElectrochim (Sat Jan 18 13:50:02 EST 2014)
Of course the strong oxidizing power of photo-generated holes, the chemical inertness and the non-toxicity of nanostructured TiO2 have made it superior photo-catalyst. Most research work have concentrated on working to understand the reactive sites for gas-solid or liquid-solid interfacial reactions. However, little attention have been paid to the light induced conversion of the physical and chemical characteristics of the surface itself. I mean conversion from hydrophobic to amphiphlic that is induced by UV illumination. This may significantly affect nitrogen doping. See Wang J. Phys. Chem B 103 2188 1999.
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