Advertisement

If you have an ACS member number, please enter it here so we can link this account to your membership. (optional)

ACS values your privacy. By submitting your information, you are gaining access to C&EN and subscribing to our weekly newsletter. We use the information you provide to make your reading experience better, and we will never sell your data to third party members.

ENJOY UNLIMITED ACCES TO C&EN

Environment

Newscripts

Surprise! It’s mercury

by Matt Davenport
December 4, 2017 | A version of this story appeared in Volume 95, Issue 48

When a bar rag just won’t cut it

[+]Enlarge
Credit: Theodore Gray/periodictable.com
Little brown jugs—like this one from Theodore Gray’s personal collection—are to be used as college football trophies, not mercury containers.
A photograph of an old ceramic jug labeled “mercury.”
Credit: Theodore Gray/periodictable.com
Little brown jugs—like this one from Theodore Gray’s personal collection—are to be used as college football trophies, not mercury containers.

A person walks into a bar carrying a jar filled with more than 5 kg of mercury.

Although we wish we could follow that sentence with a punch line, this actually happened in Armstrong, Iowa, in 2012. And it gets worse. The jar spilled.

Thankfully, nobody was hurt, but it took Environmental Protection Agency contractors a week to fully clean the spill. Among the remediation highlights, workers had to remove the bar’s flooring and treat several appliances in one of the patron’s houses as hazardous waste, including the washer, dryer, and vacuum cleaner.

A group of public health officials earlier this year wrote about this and several other mercury spills, cluing the Newscripts gang into just how often people accidentally—and avoidably—expose themselves to this neurotoxic element (Morb. Mortal. Wkly. Rep. 2017, DOI: 10.15585/mmwr.mm6610a3). The authors counted more than 60 nonthermometer mercury spills in five states between 2012 and 2015. Corresponding author Ryan J. Wozniak tells us that he and his colleagues cataloged these cases to raise awareness about the liquid metal.

“We find that many people still have old jars of mercury in their garages, basements, and other storage areas,” says Wozniak, a toxicologist at the Wisconsin Department of Health Services. That’s in addition to other mercurial sources people may have in their houses, including compact fluorescent light bulbs, old boiler heating systems, and grandfather clocks with mercury pendulums.

[+]Enlarge
Credit: Dave Roberts/periodictable.com
The element formerly known as hydrargyrum.
A photograph of a small pool of mercury is bordered by the element’s abbreviation, atomic weight, and atomic number.
Credit: Dave Roberts/periodictable.com
The element formerly known as hydrargyrum.

As elemental mercury is accessible and fascinating, spills like the Iowa case aren’t that surprising, Wozniak says. And it doesn’t help that people tend to underestimate its health effects, which typically come from chronic exposure.

Spills, however, can result in long-term exposure if the challenging and expensive cleanups aren’t handled properly. What’s more, spillage can release quicksilver into the environment, where it can accumulate and remain a threat, says Noelle Eckley Selin, who studies persistent pollutants at Massachusetts Institute of Technology.

For example, the element can build up in seafood as toxic methylmercury in some ecosystems. “Mercury doesn’t just go away,” she says. “Smaller spills certainly do add up.”

As for what motivates someone to bring 5 kg of the glittery substance into a bar, Wozniak doesn’t hazard a guess. But the polymath Theodore Gray—who gave Oliver Sacks about 4.5 kg of mercury on the famed neurologist’s 80th birthday—shares some insight on that front.

“I can totally see myself doing that,” he tells Newscripts of bringing a jug of mercury into a bar. “I don’t know why that guy did it, but if I did, it would be to let people experience the mind-blowing density of mercury.” Five kilos of mercury is less than two cups, he explains. For comparison, two cups of water has a mass of about 500 g.

Gray, however, knows how to handle his ooze. He stores mercury in thick-walled, rubber-coated, shatterproof reagent bottles, which are stored in secondary containers. “I might take 12 lbs of mercury into a bar, but I certainly wouldn’t take any chances with it spilling,” he says. “One should not fear the substance, only the ignorance that leads to its mishandling.”

Matt Davenport wrote this week’s column. Please send comments and suggestions to newscripts@acs.org.

Article:

This article has been sent to the following recipient:

0 /1 FREE ARTICLES LEFT THIS MONTH Remaining
Chemistry matters. Join us to get the news you need.