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Coatings

Liquid film self-heals and sticks to metals

Network of graphene microcapsules stabilizes oil films, enabling coating to repair itself repeatedly

by Mitch Jacoby
February 10, 2019 | APPEARED IN VOLUME 97, ISSUE 6

 

09706-scicon7-healed.jpg
Credit: Jiaxing Huang/Northwestern
Scratching (left) an oil film thickened with microcapsules (black) triggers a brief oil flow that repairs the damage in seconds (right).

Scratching an oil film with a hard object exposes the underlying surface, but only briefly. The oil flows quickly and reestablishes a continuous film. The flow properties make oil films self-healing, which is desirable for protective coatings on metals, for example. But the same property prevents the film from remaining in place. Increasing the viscosity can pin the film to the metal surface, but it slows the healing process. With a nod to Shakespeare, Jiaxing Huang of Northwestern University sums up the dilemma this way: To flow or not to flow, that is question. His group just came up with a solution that enables oil films to do both—flow and not flow (Research 2019, DOI: 10.1155/2019/3517816). By using a spray-drying procedure, Huang, Alane Tarianna O. Lim, and coworkers formed a network of interconnected graphene microcapsules with 10 nm thick walls and 250 nm voids. Tests show that adding a small amount of the microcapsules (5 wt %) to silicone oil increases the oil’s viscosity by a factor of 1,000, causing films to remain on metal surfaces. Scratching the films ruptures the capsules, allowing oil to flow quickly but briefly as the network repairs itself and halts the flow. In contrast to some polymers that exhibit self-healing only on a microscopic scale, the water- and acid-resistant liquid film heals macroscopic damage, even after scratching the same spot 200 times.

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