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Nanomaterials

Polar bears inspire strong, elastic, heat-insulating aerogel

Made of hollow carbon tubes, the durable insulator outperforms most aerogels

by Prachi Patel, special to C&EN
June 9, 2019 | APPEARED IN VOLUME 97, ISSUE 23

09723-scicon7-polar.jpg
Credit: Chem
These hollow carbon tubes form a pliable aerogel.

A polar bear’s shaggy coat provides exceptional defense against icy, Arctic conditions. Each hollow strand of fur traps heat, collectively forming a waterproof mat that keeps the animals warm and dry. Inspired by this structure, researchers have made a strong, insulating aerogel that is also elastic and waterproof (Chem 2019, DOI: 10.1016/j.chempr.2019.04.025). Materials that mimic polar bear hair could be used for thermal and sound insulation in buildings and airplanes, but they tend to be weak and not very pliable, limiting applications. So, Shu-Hong Yu, a chemist at the University of Science and Technology of China, turned to tough carbon tubes, which are thicker than common nanotubes. Working with Yong Ni, Jian-Wei Liu, and colleagues, Yu soaked 35 nm wide, 5 µm long tellurium nanowires in a glucose solution and heated them, creating a mesh of interconnected wires with a smooth carbon shell. The group then heated the material in an inert atmosphere to remove the nanowires, yielding a carbon-based aerogel. The product is lighter and traps heat better than most aerogels and commercial insulators, Yu says. It also bounces back and does not lose its insulating nature when squished more than 10,000 times to 10% of its volume. The team aims to cut production costs by finding an inexpensive substitute for the tellurium nanowire template.

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