Safer Chlorine Transfer | Chemical & Engineering News
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Web Date: June 20, 2007

Safer Chlorine Transfer

Chemical safety board urges use of remotely operated equipment
Department: Government & Policy

Emergency protective equipment at facilities that unload chlorine from railroad tankers is inadequate and should be changed, says the Chemical Safety & Hazard Investigation Board (CSB) in a recent safety bulletin.

On the basis of its investigations, CSB also recommends that the Department of Transportation expand its regulatory coverage to facilities that unload chlorine railcars and require the facilities to install remotely operated emergency isolation devices to quickly shut down the flow of chlorine if a hose ruptures or another failure of unloading equipment occurs.

The board notes that rail tank cars are equipped with internal valves that stop flow when an accident occurs during transit, but these systems are not designed to stop leaks during unloading. A failure of a transfer railcar hose may not activate these emergency valves, the board says.

A CSB investigation of a 2002 accident at DPC Enterprises in Festus, Mo., for instance, found that when a transfer hose ruptured, the emergency shutdown valve also failed. As a result, emergency responders were forced to walk through a 4-foot deep fog of chlorine vapor to manually close a shutdown valve on top of the railcar. Some 68 residents sought medical aid; 48,000 lb of chlorine was released.

The board notes that a survey of bulk chlorine users found that 30% of them relied solely on transit-based emergency valves without remote shutoffs to stop chlorine flow when a hose ruptures. The bulletin is available at

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