Advertisement

If you have an ACS member number, please enter it here so we can link this account to your membership. (optional)

ACS values your privacy. By submitting your information, you are gaining access to C&EN and subscribing to our weekly newsletter. We use the information you provide to make your reading experience better, and we will never sell your data to third party members.

ENJOY UNLIMITED ACCES TO C&EN

Analytical Chemistry

'Infofuse' Gets Message Across

New technology transmits chemically encoded messages

by Sophie L. Rovner
June 1, 2009 | A version of this story appeared in Volume 87, Issue 22

When an infofuse is lit, a succession of metallic dots burn (from top to bottom), producing a series of spectral signatures that can convey an encoded message.
[+]Enlarge
Credit: Courtesy of George Whitesides
Credit: Courtesy of George Whitesides

Chemically coded flares may one day join the ranks of telecommunication methods. In a chemical analog of Morse code transmission, burning a metal-treated material reveals a message to a remote viewer. Harvard University chemistry professor George M. Whitesides, postdoc Samuel W. Thomas III, and their colleagues devised the chemical communication technique, which they call an "infofuse" (Proc. Natl. Acad. Sci. USA, DOI: 10.1073/pnas.0902476106).

With further development, this proof-of-concept technology could be used in applications such as a device to transmit information during a rescue operation, Thomas says. Or it could be combined with a sensor in a device that would transmit a warning signal when, say, a pollutant was detected in the environment, he adds.

The researchers encode a message by applying a succession of dots of various alkali metals on a fuse made of a nitrocellulose strip. To demonstrate the concept, they created a code in which a particular combination of metal dots corresponds to a particular alphanumeric character. The letter c, for example, is represented by a dot of lithium and rubidium followed by a dot of cesium.

Once the message is ready to send, the fuse is lit. As the flame moves through the nitrocellulose strip, each successive metallic dot burns and emits light of characteristic wavelengths. A spectrometer or camera ascertains which wavelengths are successively emitted, thereby revealing the identity and order of metals that had been placed along the strip.

Currently, the signal is detectable as far as 600 meters from the fuse, Thomas says. He believes this limit could be stretched beyond 1 km. Signals of greater complexity could be encoded by utilizing other properties of light, such as intensity, he adds.

No external power such as a battery or electricity is needed to encode or send messages: The metals can be dotted on the fuse by hand, and message transmission merely requires a flame. A. Prasanna de Silva, who studies molecule-based information transfer at Queen's University of Belfast, in Northern Ireland, believes the work is significant because until now, "no such self-powered information systems that transmit over fair distances" have been developed.

Advertisement

Article:

This article has been sent to the following recipient:

0 /1 FREE ARTICLES LEFT THIS MONTH Remaining
Chemistry matters. Join us to get the news you need.