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Biological Chemistry

Firefly inspires brighter LEDs

Future displays that glow like fireflies could use less energy

by Katherine Bourzac
April 19, 2016

Scanning electron micrographs of firefly lantern surfaces and firefly-inspired manmade LED surface materials.
Credit: Nano Lett.
Firefly lantern organs (left) are covered with tiled microstructures decorated with nanoscale ridges that together make the light shine brighter. A manmade mimic (right) has the same effect.

An organic light-emitting diode that mimics the three-layered structure of a firefly’s lantern shines brighter than previous designs (Nano Lett. 2016, DOI: 10.1021/acs.nanolett.5b05183). The bioinspired OLED could be used to make TVs and computer screens that use less energy.

Ki-Hun Jeong of the Korea Advanced Institute of Science & Technology and colleagues started by studying firefly lanterns. Previous studies had established that micro- and nanostructures in the chitin cuticle covering these creatures’ tail-end lantern organs help improve light transmission. The refractive index of the structured cuticle more closely matches that of the air than smooth chitin does, helping fireflies make stronger beams of light. The structures also reduce internal reflection. In 2012, Jeong’s group used these principles to make a cuticle-inspired, spherical lens to mount over an LED, boosting light transmission (Proc. Natl. Acad. Sci. U.S.A., DOI: 10.1073/pnas.1213331109).

Jeong wanted to build a better firefly-based system, this time integrating the insect-inspired optics into the design of an organic LED. Jeong sought a flat design that could be used in TV and cellphone displays. For this work, Jeong turned to a species of firefly, Pyrocoelia rufa, that has structures 10 µm wide inclined at an angle of 5 °covering the cuticle like roofing tiles. The lantern is further decorated with thin ridges running lengthwise, 150 nm wide and 250 nm apart. Below the cuticle is a layer of tissue that produces light and sends it in all directions, while below that is a layer that acts as a mirror, reflecting the light upward and out of the lantern.

Photographs of green organic LEDs, one with a firefly-inspired coating, and one without.
Credit: Nano Lett.
A green organic LED with a coating that mimics the surface of a firefly lantern shines 60% brighter than a standard green LED.

Jeong and his group mimicked these three layers in a design for a green OLED. The top layer is a polymer resin patterned with structures of the same dimensions as those that cover the cuticle. Below that lies a layer of the light-emitting material used in standard OLEDs, and under that, an aluminum reflector backs the OLED.

The bioinspired OLED shines about 60% brighter for the same amount of power compared to a conventional green OLED, Jeong says. And it emits the light over a broader angle, which could improve OLED TVs, giving them a larger viewing angle. So far Jeong’s team has made firefly-inspired OLEDs that emit green light at the same wavelength as the insects’ luminescence. To make a full display they’d need to tailor the pattern dimensions to work with red and blue pixels.

Akhlesh Lakhtakia, who develops biomimetic optics at the Pennsylvania State University, says it should be possible to make the bioinspired OLEDs at industrial scale for use in lighting and displays. But engineers now have to figure out whether the payoff in efficiency with a biomimetic design is worth the extra expense of redesigning how they make TV screens and light bulbs.

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