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Energy Storage

New battery could serve the grid

Manganese-hydrogen design boasts high capacity, long life, and the promise of low cost

by Prachi Patel, special to C&EN
May 1, 2018

A schematic explains how the battery works, showing manganese ions depositing on the battery cathode during a charging cycle.
Credit: Nat. Energy
During charging in the new battery, manganese ions (red) from the manganese sulfate electrolyte solution deposit on the carbon-fiber-based fabric (green) at the cathode while the platinum catalyst (yellow) at the anode fabric (purple) produces hydrogen gas from water. The process is reversed during discharge.

A new battery made of manganese and hydrogen could be easily scaled up to store energy for the grid, researchers say. The battery houses a large amount of energy, lasts a long time, and could be inexpensive enough for the job.

Finding the perfect battery for grid storage remains a holy grail for researchers. The ideal grid battery should pack a lot of energy into a small volume and, per the U.S. Department of Energy’s requirements, store each kilowatt-hour of energy for $100 or less. It also needs a long life, says Yi Cui, a professor of materials science and engineering at Stanford University. “You want them to run for 10,000 charging cycles or more, so they can last 25 years.”

Most current battery technologies fall short in at least one area. Lithium-ion batteries that power laptops and electric cars have energy densities of over 200 Wh/kg, but cost more than twice the DOE requirements. Redox-flow batteries are also expensive. Meanwhile, lead-acid batteries are cheap but they last only 500 cycles and their energy densities are subpar. Researchers have recently made low-cost batteries with aqueous solutions of zinc and sodium ions as electrolytes, but they also suffer from low energy density and short cycle life.

Cui’s group turned to abundant manganese. He says the new battery meets all the critical needs for the grid. It has the potential to be low cost because manganese and hydrogen are abundant. It has an energy density of around 140 Wh/kg, thrice that of lead-acid. And it boasts a very long life of more than 10,000 cycles (Nat. Energy 2018, DOI: 10.1038/ s41560-018-0147-7).

A diagram depicts how the anode and cathode are fitted into a steel cylinder the size of a regular C battery. A photo of the battery is also shown.
Credit: Nat. Energy
A prototype manganese-hydrogen battery cell (photo, right) consists of a carbon cathode (green) rolled around the inside of a steel cylinder and a small platinum-loaded carbon anode (gray) in the middle, with the space in between filled with an aqueous electrolyte.

The new battery has an anode made of carbon-fiber-based fabric loaded with platinum catalyst. The cathode is a plain carbon fabric, and the electrolyte is an aqueous solution of manganese sulfate. When the battery charges, hydrogen gas bubbles up as the platinum catalyst reduces water at the anode. Meanwhile, manganese ions from the electrolyte combine with the oxygen and deposit on the cathode as solid manganese dioxide. The reverse happens during discharge: manganese ions dissolve back into the electrolyte, hydrogen gets oxidized to form water, and electrons travel through the external circuit.

To make a battery cell, the researchers rolled a piece of the cathode and attach it inside a stainless steel cylinder about the size of a standard C battery. They clamped a small anode piece in the middle of the vessel, filled the gap between the electrodes with electrolyte, and sealed the cell.

“The device is already much bigger than ones usually tested in laboratories and is highly scalable,” Cui says. Practical devices will be larger versions of their lab-scale cousin, with large pressurized steel tanks to hold hydrogen. The team has developed low-cost catalysts to replace platinum and is now experimenting with other cathode materials to further improve battery performance.

This battery is similar to the nickel-hydrogen batteries used to power satellites, says Ping Liu, who designs materials for energy storage at the University of California, San Diego. Those have impressively long lives of 20,000 cycles, but are costly. The new manganese battery could face the same challenge. “Tank size will be a critical consideration,” he says. “Tanks are costly and bulky.” Nevertheless, he adds, “these aren’t insurmountable issues. If they can find a solution, then material cost is extremely low.”



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