Rethinking Zircon For Nuclear Waste | Chemical & Engineering News
Volume 85 Issue 3 | p. 45 | Concentrates
Issue Date: January 15, 2007

Rethinking Zircon For Nuclear Waste

Department: Science & Technology

Plans for using ceramics made of the mineral zircon (ZrSiO4) to store hazardous 239Pu nuclear waste may have hit a dead end. A new study suggests that zircon is far more susceptible to the damaging effects of α radiation than originally thought; the finding presents a problem for zircon's use in long-term storage of 239Pu, an α-emitter with a 24,110-year half-life (Nature 2007, 445, 190). Ian Farnan of the University of Cambridge and Herman Cho and William J. Weber of Pacific Northwest National Laboratory came to that conclusion when they used NMR spectroscopy to assess how much damage occurs to zircon when it's doped with 239Pu and the shorter lived 238Pu. They found that each α-decay event displaces about 5,000 atoms, far more than the 1,000-2,000 displacements predicted by standard simulations. That rate of decay would render zircon containing 10% 239Pu by weight an amorphous material after only 1,400 years-far less than the 250,000-year time scale desired.

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