Treating Nuclear Waste With Sulfides | Chemical & Engineering News
Volume 86 Issue 10 | p. 54 | Concentrates
Issue Date: March 10, 2008

Treating Nuclear Waste With Sulfides

Department: Science & Technology
K<sub>2</sub>xMnxSn<sub>3-</sub>xS<sub>6</sub>
Credit: © 2008 PNAS

Metal sulfides may make it easier to remove radioactive strontium-90 from nuclear waste (Proc. Natl. Acad. Sci. USA, DOI: 10.1073/pnas.0711528105). To minimize the need for waste storage space, handlers would like to be able to remove 90Sr from bulk waste so they can immobilize and store just the radioactive component. Common adsorbents, however, may decompose in the extremely alkaline environment of many waste streams. These streams also have high salt concentrations that challenge selective uptake of Sr2+. Now, a research group led by Mercouri G. Kanatzidis of both Northwestern University and Argonne National Laboratory has found that layered metal sulfides may circumvent those problems. The material, K2xMnxSn3-xS6 (x = 0.5-0.95, shown), is composed of MnS6 and SnS6 octahedra connected through the sulfur ligands with exchangeable K+ ions located between the layers. The researchers found that the layered sulfide removed more than 92% of Sr2+ from solutions ranging from pH 3.2 to pH 14.0. The material was also selective for Sr2+ in strongly alkaline environments incorporating cations from Groups 1 and 2.

 
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