If you have an ACS member number, please enter it here so we can link this account to your membership. (optional)

ACS values your privacy. By submitting your information, you are gaining access to C&EN and subscribing to our weekly newsletter. We use the information you provide to make your reading experience better, and we will never sell your data to third party members.



Sila-Explosive's Sensitivity Explained

Chemists pinpoint a mechanistic reason why the silicon analog of the explosive pentaerythritol tetranitrate is much more shock-sensitive

by Elizabeth K. Wilson
May 25, 2009 | A version of this story appeared in Volume 87, Issue 21

Why is the silicon-based explosive silicon pentaerythritol tetranitrate (Si-PETN) so sensitive? Except for the central atom, which is silicon instead of carbon, Si-PETN is identical to the commercial explosive pentaerythritol tetranitrate (PETN). Yet Si-PETN's propensity for exploding at the slightest touch makes it too dangerous for practical use. Caltech's William A. Goddard III, Thomas M. Klapötke of Ludwig Maximilian University, in Munich, Germany, and colleagues now think they've identified the source of Si-PETN's unique reactivity (J. Am. Chem. Soc., DOI: 10.1021/ja809725p). Using density functional theory, the group studied the energetics of a number of different decomposition pathways for PETN and Si-PETN. Although most of these pathways were energetically similar for the two compounds, one pathway's energetics differed dramatically. Both compounds can undergo a rearrangement in which a methylene group and the adjacent oxygen from one of the molecules' four CH2ONO2 branches switch places—the oxygen atom ends up bonded to the central atom. This process has a much lower energy barrier and is more exothermic for Si-PETN than PETN. The researchers say this is because the Si–O bond is much stronger than the C–O bond, and also because silicon is much larger than carbon, making the rearrangement transition state more stable.


This article has been sent to the following recipient:

Chemistry matters. Join us to get the news you need.