Volume 87 Issue 45 | p. 4 | Letters
Issue Date: November 9, 2009

Early Azide Explosion

Department: Letters

Steven V. Ley's letter reminded me of a similar accident that occurred in the late 1940s at a company where I worked as a control chemist (C&EN, June 8, page 4). Although I was not a witness, I seem to remember that the chemical operator was adding sodium azide to a reactor. The process had been in trial use for six months without a glitch or difficulty.

It was midmorning, and an approved crew composed of personnel from research, pilot plant, the safety department, and others had gathered around the open reactor to approve the process when the batch exploded. Seven employees were killed, and others were badly injured. Just as Sheldon Crane reported in his earlier letter, the cause of the explosion was unknown (C&EN, April 13, page 2; June 8, page 4; and July 13, page 2).

I remarked at the time that the cause of the explosion must have been wet methanol, the solvent in the reactor. In my department, we used Karl Fischer reagent to detect water in methanol. We made the reagent in the control laboratory attached to manufacturing by using a standard cylinder of SO2 that was safely locked in place. Our safety engineer, a Navy veteran, was nicknamed "red tag" because he was a stickler for safety in the process. Karl Fischer reagent was standardized at the beginning of every shift as the first job of the shift because the reagent deteriorates with time.

I have always suspected the control chemist was so busy cleaning up the laboratory before the inspection that he forgot to restandardize the Karl Fischer reagent and passed the methanol as being anhydrous. Even an unopened bottle of reagent-grade methanol could be suspect if it has not been tested for moisture before being used. Like metallic sodium, sodium azide and magnesium nitride are unforgiving when added to wet methanol.

Because of labor shortages during World War II, most of the control chemists where I worked were hired after they graduated from high school. I was one of the first college graduates to be hired and quickly rose to group nine on the company pay scale; research hired their chemists with master's degrees at the group-five level and paid them poorly, knowing that after several years they would go back to graduate school.

College—oops—university chemistry laboratories are some of the most dangerous places on campus. I hope that chemistry department heads read this letter.

Robert Seibert
Boerne, Texas

 
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Comments
sateesh (Tue Sep 16 07:41:13 EDT 2014)
Very good information.

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