UNIQUE RECOVERY | Chemical & Engineering News
Volume 90 Issue 47 | p. 15
Issue Date: November 19, 2012

Cover Stories: Coal’s Enduring Power

Unique Recovery: Clean-Coal Plant Turns Out Natural Gas And Chemicals

Department: Business
Keywords: coal, natural gas, emissions, mercury, nitrogen oxides, carbon dioxide, pollution control
Dakota Gasification plant produces gas and chemicals from coal.
Credit: Basin Electric Power Cooperative
Dakota Gasification plant.
Dakota Gasification plant produces gas and chemicals from coal.
Credit: Basin Electric Power Cooperative

Utilities looking to recover pollutants in the form of salable chemicals would do well to study Dakota Gasification. At its site in Beulah, N.D., Dakota turns coal into synthetic natural gas for power generation and heating. By-products that might otherwise be emitted into the atmosphere are converted into valuable chemicals.

“We are profitable, but depending on the price of gas, by-product chemicals keep our earnings stable,” says a spokeswoman for Dakota, which is owned by Basin Electric Power Cooperative, an electric utility.

Last year, Dakota consumed 6 million tons of lignite coal and had about $520 million in sales evenly split between synthetic natural gas and chemicals such as ammonia, ammonium sulfate fertilizer, phenol, and naphtha.

The plant uses 14 gasifiers to break down coal in the presence of oxygen and steam into a raw gas. The gas is cooled to remove tar oil, phenol, ammonia, and water. Other impurities such as carbon dioxide and sulfur dioxide are removed before 145 million cu ft of gas per day enters pipelines for national distribution to utilities and homes.

Carbon dioxide is captured in the Rectisol process, which uses methanol to absorb and separate CO2 and other impurities from the synthetic gas. Dakota sends about 152 million cu ft per day of the captured CO2 via a 205-mile pipeline to the Saskatchewan oil fields to enhance recovery of oil from wells. Sulfur dioxide captured from the flue gas is converted to ammonium sulfate.

Tar oil recovered in the gasification process was formerly used as fuel in the plant’s boiler. Dakota just completed work on a stripper tower to remove water and light hydrocarbons from the tar oil to upgrade it into more valuable fuel oil. The plant will now burn more synthetic gas in its boilers instead.

Another project now in the planning stage is a 1,100-ton-per-day granular urea fertilizer plant, which could begin operating in 2016. The project would draw on anhydrous ammonia currently made at the site from synthetic gas when gas prices are low.

The Beulah plant, known as the Great Plains Synfuels Plant, was built by a consortium of energy companies between 1980 and 1984. Basin Electric Power Cooperative purchased the plant in 1988 from the federal government after the consortium reneged on government loans supporting the plant during a period of low natural gas prices.

Only one other plant similar to Dakota’s plant exists today: a coal-to-liquids facility operated in South Africa by Sasol, the Dakota spokeswoman says.

Construction costs of both facilities were high enough that others may not be willing to replicate the plants. Over the years, Basin Electric and the original owners invested about $2.1 billion to build the Beulah plant. A similar facility today would cost about $4 billion, the spokeswoman says.

Chemical & Engineering News
ISSN 0009-2347
Copyright © American Chemical Society
C King (Mon Nov 19 10:09:12 EST 2012)
Sounds to have a lot of parallels to the 19th century coal gasification plants which many small and large towns operated in Europe. Coal tar was significant in the development of the organic chemical industry. Hence the old phrase "coal tar dyes".

It would have been interesting if the article had highlighted the differences between the old and the new processes.

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