Molten Nuclear Fuel Structure Could Help Prevent Meltdowns | Chemical & Engineering News
Volume 92 Issue 47 | p. 24 | Concentrates
Issue Date: November 24, 2014

Molten Nuclear Fuel Structure Could Help Prevent Meltdowns

X-ray synchrotron radiation studies reveal dynamic details of how UO2 transitions from a solid to a molten liquid
Department: Science & Technology
News Channels: Materials SCENE, Analytical SCENE
Keywords: uranium dioxide, nuclear waste, structure, molten
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Uranium dioxide structures shown at 2,100 K and in liquid form at 3,270 K. The molten material contains UO6 (black) and UO7 (light blue) polyhedra.
Credit: Science
Uranium dioxide structures at different temperatures.
 
Uranium dioxide structures shown at 2,100 K and in liquid form at 3,270 K. The molten material contains UO6 (black) and UO7 (light blue) polyhedra.
Credit: Science

Scientists have for the first time obtained X-ray structures that reveal the dynamics of the nuclear fuel uranium dioxide as it transitions from a solid to its molten state (Science 2014, DOI: 10.1126/science.1259709). Researchers have previously relied on computer models to investigate the behavior of molten UO2, but the descriptions haven’t been consistent. This relative dearth of knowledge has hindered the ability to predict properties important for reactor safety, such as viscosity and compressibility of the material. Lawrie B. Skinner at Argonne National Laboratory and colleagues used synchrotron X-ray diffraction studies to probe UO2 beads heated by a laser. Solid UO2 forms crystals made of UO8 cubic polyhedra. The group found that as the solid heats up to 2,670 K it undergoes a so-called lambda transition in which oxygen becomes increasingly disordered and the material’s heat capacity and thermal conductivity rise sharply. When the solid actually melts, at 3,270 K, the number of oxygen neighbors close to each uranium drops, forming structures composed largely of UO6 and UO7.

 
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