If you have an ACS member number, please enter it here so we can link this account to your membership. (optional)

ACS values your privacy. By submitting your information, you are gaining access to C&EN and subscribing to our weekly newsletter. We use the information you provide to make your reading experience better, and we will never sell your data to third party members.


Analytical Chemistry

A Supramolecular Approach to Thwarting Counterfeiters

Supramolecular Chemistry: The colors of fluorescent inks based on heterorotaxane molecules can be tuned to create virtually unforgeable tags

by Bethany Halford
April 27, 2015 | A version of this story appeared in Volume 93, Issue 17

Fighting forgeries, whether bogus banknotes or high-priced handbag knockoffs, has become a complex chemical and engineering arms race. Once a counterfeiter figures out how to mimic a security feature, such as a fluorescent tag, that feature essentially loses its value. Northwestern University chemists led by J. Fraser Stoddart have come up with novel security inks based on supramolecular chemistry that they believe will be especially difficult to duplicate (Nat. Commun. 2015, DOI: 10.1038/ncomms7884). The inks are based on a heterorotaxane molecule—a linear moiety threaded through two or more different cyclic moieties. The heterorotaxane is pale yellow under natural light but glows dark red in ultraviolet light. Adding cyclodextrin to the compound changes the fluorescent hue across a rainbow of colors, depending on how much cyclodextrin is added. The resulting array of inks can be printed in myriad images on the authentic item and verified with a UV lamp and a smartphone. What’s more, the images can also be authenticated with a library of indicators that cause the inks to change color. So even if a counterfeiter is able to mimic the original fluorescent colors, the authentication color changes would be nearly impossible to fake.

Credit: Stoddart Group
A bar code made with novel security inks glows in a variety of colors under ultraviolet light.
A barcode coated with heterorotaxane-based security inks glows in multiple colors under ultraviolet light.
Credit: Stoddart Group
A bar code made with novel security inks glows in a variety of colors under ultraviolet light.


This article has been sent to the following recipient:

Chemistry matters. Join us to get the news you need.