Nuclear Forensics Shows Nazis Were Nowhere Near Making Atomic Bomb | October 5, 2015 Issue - Vol. 93 Issue 39 | Chemical & Engineering News
Volume 93 Issue 39 | pp. 30-31
Issue Date: October 5, 2015

Nuclear Forensics Shows Nazis Were Nowhere Near Making Atomic Bomb

Analysis of historic uranium samples from Germany’s wartime experiments solves World War II mystery
Department: Science & Technology
News Channels: Analytical SCENE
Keywords: forensics, uranium, history, WWII
[+]Enlarge
FINAL REACTOR
Werner Heisenberg’s last wartime experiment, called B8, used 664 uranium cubes suspended in deuterated water as fuel. Shown here is a replica of B8’s uranium pile, on display at the Atomkeller Museum, in Haigerloch, Germany.
Credit: ArtMechanic/Wikimedia Commons
A hanging array of gray cubes strung on about 30 cords dangles above a pit.
 
FINAL REACTOR
Werner Heisenberg’s last wartime experiment, called B8, used 664 uranium cubes suspended in deuterated water as fuel. Shown here is a replica of B8’s uranium pile, on display at the Atomkeller Museum, in Haigerloch, Germany.
Credit: ArtMechanic/Wikimedia Commons

Today’s nuclear forensic scientists are typically concerned with detecting radioactive materials being smuggled across borders or tracking down the facilities where those materials originated. But recently, nuclear scientists turned their investigative skills to a nagging question from the annals of science history: During World War II, were the Germans close to achieving a working nuclear reactor?

By analyzing a uranium cube uncovered in the 1960s that had been used in Germany’s nuclear program during the war, the scientists—led by Maria Wallenius of the European Commission’s Institute for Transuranium Elements, in Karlsruhe, Germany—determined that the Germans weren’t even close (Angew. Chem. Int. Ed. 2015, DOI: 10.1002/anie.201504874).

The uranium cube in question was suspected to be part of famed physicist Werner Heisenberg’s last wartime experiment, called B8, which took place in March 1945. In that experiment, carried out near Haigerloch, Germany, 664 uranium cubes suspended in deuterated, or “heavy,” water were used as fuel. The U.S. military’s Alsos Mission recovered most of those cubes in April 1945. But a few of them went missing. Two decades later, several uranium cubes—presumed to have been part of B8—were discovered in southern Germany.

In addition to analyzing one of the cubes, Wallenius and coworkers also analyzed a uranium plate that Heisenberg and his collaborator Karl Wirtz had used in a different reactor geometry. Heisenberg and Wirtz switched to cubes after they learned that the more compact shape worked better.

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FUEL
The uranium cube and plate shown below on millimeter-grid paper were part of the German wartime nuclear program.
Credit: Angew. Chem. Int. Ed.
A gray plate.
 
FUEL
The uranium cube and plate shown below on millimeter-grid paper were part of the German wartime nuclear program.
Credit: Angew. Chem. Int. Ed.

Wallenius and her group had a number of questions about the materials they wanted to answer. Where did the ore used to produce the plate and cube come from and when was it processed? Were the samples enriched in uranium-235, and had they been exposed to a major source of neutrons? The answer to that last question, in particular, would help them figure out whether Germany was close to achieving a sustained chain reaction and, thus, a bomb during World War II.

The researchers found evidence to help answer each of those questions by determining different isotope ratios within the materials.

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Credit: Angew. Chem. Int. Ed.
A gray plate
 
Credit: Angew. Chem. Int. Ed.

To determine the source of the ore, they measured the strontium isotope ratio and the pattern of rare-earth elements in the cube and plate and compared them to samples of ores from uranium mining regions that Germany was known to have had access to during the war: the Joachimsthal region in the former Czechoslovakia and the Shinkolobwe mine in the former Belgian Congo. Germany gained access to uranium from Shinkolobwe after it seized Belgium’s uranium supply. Measurements taken by Wallenius and her group suggest that both the cube and the plate were made of uranium from Czechoslovakia.

To date the materials, they used the ratio of thorium-230 to uranium-234 to determine the last time the uranium underwent chemical processing. Such separations typically remove impurities and decay products such as thorium-230. The isotope ratios pin the dates to late 1943 for the cube and mid-1940 for the plate, suggesting that the samples were in fact part of Germany’s nuclear program during World War II. They also help confirm the order in which the Germans adopted various reactor designs—first plates, then cubes.

From the ratios of the various uranium isotopes— 234U, 235U, 236U, and 238U—Wallenius and coworkers learned that the samples were not enriched in 235U. Increased levels of this low-abundance, fissionable form of uranium would have made it easier to sustain a nuclear chain reaction.

The amount of another uranium isotope, 236U, taken together with the amount of plutonium-239, serves as an indicator of a sample’s past neutron bombardment. This is because 236U forms when 235U captures neutrons, and 239Pu forms when 238U captures neutrons and undergoes beta decay. If the samples had been exposed to a large number of neutrons, as would be found in a working nuclear reactor, their levels of 236U and 239Pu would have thus been elevated relative to their natural abundances.

The amount of 236U in the samples was so small that Wallenius and her coworkers couldn’t detect it with their instrumentation and had to send the samples to Australia and Austria to be measured by accelerator mass spectrometry, a more sensitive technique.

Not only were the levels not elevated, the 239Pu level was even lower than would be expected naturally. Wallenius suspects that the low 239Pu resulted from the chemical separations used to process the ore.

“When uranium is chemically processed, most of the other elements are removed,” she says. “That means also at least some of the plutonium coming from nature was removed.”

These findings help bolster the argument that Germany was not on the verge of having a working reactor during World War II. “The report corroborates the observations of the Alsos Mission’s team and long-held assumptions by Manhattan Project historians about the fledgling efforts made to develop an atomic bomb under Nazi Germany,” says Cynthia C. Kelly, president of the Atomic Heritage Foundation, in Washington, D.C.

For now, forensics has wrung all the information it can from these samples. But Wallenius doesn’t rule out returning to them in the future. “Nuclear forensics is still an evolving discipline,” she says. “We continue to develop or look at new parameters that may tell us more of the history of our nuclear forensic samples.”  

 
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Comments
Dr. Donald Ray Anderson (September 30, 2015 3:16 PM)
Very insightful article. I worked in the nuclear industry for many years and learned something today that I never knew before. I'm an 80-year old retired chemist/editor/linguist and still learning something new every day thanks to the Internet
Simon Gunson (June 13, 2016 8:22 AM)
There are several false assumptions made in this article. First that Nazi research into nuclear reactors was also their pathway to developing nuclear weapons. That is false. Nuclear reactors were the focus of the civilian Uranverin II headed by Heisenberg and later by Gerlach.

Uranium enrichment by Ultra-centrifuge for Atomic weapons were the focus of Heereswaffenamt (German Army Research Dept) under Diebner. Therefore you cannot take a cube of un-enriched Uranium of a type known to have been used at the Atomkeller in Haigerloch by Heiseberg and deduce anything about a nuclear weapons project.

Furthermore it is also known that large amounts of these Uranium cubes which were never used in reactor experiments were buried at the end of the war and later traded on the black market, thus were never exposed to irradiation.

Dr Erich Bagge already addressed the point of Celia Arnaud's article in 1941. Dr Erich Bagge wrote in his diary after a meeting with General Professor Erich Schumann on 11 September 1941 that Uranium enrichment was not vital for developing a nuclear reactor, but it was vital for developing nuclear explosives.

This article falls short of the journalistic rigor required to draw any meaningful conclusion.

The German military embarked from the Bunsen Conference of October 1940 on development of Ultra-centrifuges to enrich Uranium for nuclear weapons. Heisenberg was entirely excluded from involvement in the Nazi nuclear weapons project therefore answered it's own assumptions without addressing the real issue. The Germans were very successful with centrifuge enrichment and are known to have developed several centrifuges under the leadership of Dr Paul Harteck
Martin Page (March 29, 2017 5:29 AM)
Initially many scientists could and did hope that some principle would emerge which would prove that atomic bombs were inherently impossible. This hope faded gradually. Smyth Report 1946.

If I have pure 235 each neutron will immediately beget two children and there must be a chain reaction which goes quickly .One neutron always makes two others in pure 235. In order to make 1024 neutrons I need 80 reactions one after the other. The mean free path is about 6 centimetres. In order to make 80 collisions, I must have a lump of radius of about 54 centimetres and that would be about a ton. Werner Heisenberg, Farm Hall transcripts 1945.

Further, in the matter of an atomic bomb, it is not considered wise for the following reasons. For it to become a large magnitude explosion, a high temperature has to be attained. In order to do this, it is necessary for a time between 1/20 to 1/30 (micro) second, that it is confined by a substantial tamper. That is to say the tamper, the weight of this thing would be enormous and because of this the opinion is that it is not suitable (as a bomb). Yoshio Nishina, Tonizo transcripts 2nd July 1943.

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