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Physical Chemistry

Alcohol And Sugar Molecule Spotted On Comet For First Time

Astronomy: Complex organics formed in nascent solar system, study suggests

by Elizabeth K. Wilson
October 25, 2015 | APPEARED IN VOLUME 93, ISSUE 42

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Credit: Fabrice Noel
Comet Lovejoy contains glycolaldehyde and ethanol.
09342-notw5-lovejoycxd.jpg
Credit: Fabrice Noel
Comet Lovejoy contains glycolaldehyde and ethanol.

Astronomers have for the first time detected ethanol and the simple sugar glycolaldehyde in a comet (Sci. Adv. 2015, DOI: 10.1126/sciadv.1500863).

The observations add to the rapidly growing roster of complex organics found in comets and bolster the theory that such molecules somehow formed on icy dust grains during early solar system formation.

The report comes on the heels of the recent discovery of four other molecules never before seen in comets: methyl isocyanate, acetone, propanal, and acetamide. The Philae lander, dispatched to the surface of the comet 67P/Churyumov-Gerasimenko by the European Space Agency’s Rosetta spacecraft, spotted those species earlier this year (C&EN, Aug. 3, page 7).

In the new experiments, Nicolas Biver, an astronomer at the Paris Observatory, in France, and colleagues obtained rotational spectra from a comet called Lovejoy using the 30-meter telescope at IRAM, in Spain’s Sierra Nevada.

Lovejoy is a particularly active comet, spewing great quantities of dust and gas into space and providing Biver’s team with a rich source of material to study. The group found signatures for 21 different molecules, including species that have already been identified in comets, such as ethylene glycol and formamide.

But although ethanol and glycolaldehyde have been observed—along with many other complex organics—in star-forming regions of space, they had never before been observed in comets.

Given that these two molecules are in the same family of compounds, such as methanol and formaldehyde that have been found in comets, the discovery is not surprising, says Jason P. Dworkin, an astronomer at the National Aeronautics & Space Administration’s Goddard Space Flight Center. Additionally, scientists have formed these species in the lab under cometlike conditions.

Dworkin says he’s looking forward to “the prospect of collecting and returning cometary ice to study in laboratories on Earth” to determine how these small molecules might have formed.

For example, NASA is considering a project called the Comet Surface Sample Return mission that will send a lander to a comet, collect a scoop of the comet’s surface, and send the sample back to Earth.

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