Iridium Conducts Selective Hydrogenolysis | Chemical & Engineering News
Volume 93 Issue 9 | p. 29 | Concentrates
Issue Date: March 2, 2015

Iridium Conducts Selective Hydrogenolysis

Catalysts selectively convert aryl alcohols and aryl methyl ethers to arenes, helping ease the use of lignin to make bulk chemicals
Department: Science & Technology
Keywords: hydrogenolysis, lignin, biomass, biobased chemical

Lignin is a bountiful biomass feedstock that could be an economical source of fuels and basic aromatic chemicals. The challenge is developing practical methods to chop up the phenolic biopolymer and then catalytically deoxygenate the resulting aryl alcohols and aryl methyl ethers. A bottleneck has been that the oxygenated aromatic rings are more susceptible to metal-catalyzed hydrogenation than they are to cleavage of the C–O bonds (hydrogenolysis). Shuhei Kusumoto and Kyoko Nozaki of the University of Tokyo may have a solution with a set of iridium hydroxycyclopentadienyl catalysts that conduct selective hydrogenolysis of aryl or methyl C–O bonds without destroying the aromatic rings (Nat. Commun. 2015, DOI: 10.1038/ncomms7296). The researchers used the catalysts (one shown) to deoxygenate substituted phenols and naphthols to benzene and naphthalene derivatives and to demethylate aryl methyl ethers to phenols. They further demonstrated the versatility of the catalysts by converting the lignin model compound vanillylacetone, which has three different C–O functional groups, to butylbenzene.

 
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ISSN 0009-2347
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