Volume 94 Issue 27 | p. 10 | Concentrates
Issue Date: July 4, 2016

Presenting a ferrocene Ferris wheel

Fused ferrocene units form redox-active nanorings that offer possibilities for host-guest, electronic, and magnetic applications
Department: Science & Technology
News Channels: Materials SCENE, Nano SCENE, Organic SCENE
Keywords: inorganic chemistry, ferrocene, Ferris wheel, oligomer, inorganic polymer
[+]Enlarge
Chemists have prepared fused ferrocene nanorings for the first time, including this six-membered version that is an organometallic analog of benzene.
Credit: Nat. Chem.
Structure of a cyclic molecule made up of six fused ferrocene units.
 
Chemists have prepared fused ferrocene nanorings for the first time, including this six-membered version that is an organometallic analog of benzene.
Credit: Nat. Chem.

By fusing ferrocene molecules together, a research team has prepared new iron-based macrocycles that resemble a Ferris wheel. Ferrocene linear chains and macrocycles have been made before, but they contained spacer groups separating the metallocene units, which don’t allow much interaction between the iron atoms. Michael S. Inkpen, Nicholas J. Long, and Tim Albrecht of Imperial College London and their colleagues have now made examples in which five to nine ferrocene units are fused by direct cyclopentadienyl C–C linkages. These redox-active ferrous/ferric nanorings have substantial charge delocalization and are more stable than previous ferrocene-based macromolecules, with the six-membered version representing an organometallic analog of benzene (Nat. Chem. 2016, DOI: 10.1038/nchem.2553). The researchers made the ferrocene rings via copper-mediated Ullmann coupling reactions of dilute solutions of iodinated ferrocene or linear ferrocene oligomers. The internal cavity of the molecules provides opportunities for host-guest chemistry, and the charge delocalization could lead to electronic and magnetic applications, the researchers say. The team is now investigating more efficient synthetic routes to the macrocycles and methods for derivatizing the rings and potentially linking them together to form large-scale arrays.

 
Chemical & Engineering News
ISSN 0009-2347
Copyright © American Chemical Society

Leave A Comment

*Required to comment