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Nanostructure boosts CO2 uptake

A highly porous magnesium boron hydride crystal sops up CO2 under mild conditions

by Katherine Bourzac
September 28, 2019 | A version of this story appeared in Volume 97, Issue 38


Structure of magnesium borohydride.
Credit: Jeffrey Urban

Jeffrey Urban and his colleagues at the Lawrence Berkeley National Laboratory noticed something surprising during their study of a potential hydrogen-storing material. When they grew magnesium borohydride on reduced graphene oxide, it formed an unusually open and porous crystalline nanostructure. “Working with the playbook of the periodic table, most inorganic crystals are dense,” Urban says. But the gamma form of crystalline magnesium borohydride (shown) is an exception. Contemplating the material’s large surface area and its plethora of exposed, reactive borohydrides, postdoc Sohee Jeong had “a chemical intuition that it would soak up CO2,” Urban says. She was right. Detailed studies revealed that the material initially works slowly, as the borohydrides first reduce the gas to create formate groups. There is then a stepwise spike in carbon dioxide uptake, forming methoxide groups (Adv. Mater. 2019, DOI: 10.1002/adma.201904252). A version of the material pretreated to create the formate groups works as well as existing CO2-scrubbing materials, but under much milder conditions. “It’s a massive thermodynamic sink for CO2,” even at ambient temperature and pressure, Urban says. He expects the material will find use in scuba-diving systems, space stations, and other enclosed spaces. But since it takes high temperatures to regenerate the material and release CO2, it would be challenging to adapt to industrial carbon capture and storage systems.


This article was updated Sept. 30, 2019, to correct the name of the researcher interviewed. It is Jeffrey Urban, not Jeffrey Long.


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