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Metal-Organic Frameworks

Chemistry In Pictures

Chemistry in Pictures: Metal-organic flowers

by Manny I. Fox Morone
December 28, 2023

A handful of crystals of a metal-organic framework that look like daisies under a microscope.
Credit: Muhammad Abbas

Muhammad Abbas found these stunning flower-like crystals when he looked at a sample of a terbium metal-organic framework (MOF) under a microscope. For new MOFs, like the one Abbas synthesized here, a typical first step involves growing high-quality crystals, key to solving their structure using X-ray diffraction analysis. Typically, these crystals grow in regular polyhedral shapes, such as cubes or dodecahedrons, but sometimes a few crystals may show irregular morphologies. However, it’s rare to see almost a whole batch of crystals grow in structures so similar and attractive as these flowers, each about 5 mm across. Abbas is exploring rare-earth MOFs for environmental applications. The goal for this project is to develop MOFs that can fluoresce when they detect pollutants in water.

Submitted by Muhammad Abbas. Follow him on X, formerly Twitter, and Instagram @MAbbas003.

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