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Web Date: December 12, 2017

EU’s chlorine makers end mercury-based production

Europe’s Dec. 11 ban brings 21 mercury cell production plants to a halt
Department: Business
Keywords: Environment, mercury, chlorine, Europe

European Union regulations requiring companies to stop making chlorine via a process that involves mercury came into effect yesterday. Of the 21 mercury technology plants that were operating at the start of 2017, seven have closed and 14 have been converted—or are about to be converted—to the less environmentally harmful membrane technology.

The seven closed plants had a combined capacity of 665,000 metric tons per year of chlorine, or 5.5% of Europe’s chlorine production capacity. The 14 plants being converted have a combined capacity of 1.4 million metric tons per year of chlorine.

EuroChlor, a trade association, estimates that since 2001 the conversion of mercury plants to cleaner technology will have cost the industry about $3.5 billion.


Mercury's demise

All of Europe's mercury-based chlorine plants are closing or converting.

Location Company Status
Belgium Inovyn Converting
Belgium Vynova Converting
Czech Republic Spolana Closed
Czech Republic Spolchemie Converting
Finland AkzoNobel Closed
France Kem One Converting
France PC Harbonnieres Closed
France PC Loos Converting
Germany AkzoNobel/Evonik New plant
Germany BASF Converting
Germany Evonik Closed
Kazincbarcika Borsodchem Converting
Italy HydroChem Italia Converting
Slovak Republic Fortischem Converting
Spain Electroquimica Onubense Converting
Spain Elnosa Closed
Spain (Flix) Ercros Closed
Spain (Vilaseca) Ercros Converting
Spain Inovyn Closed
Spain Solvay Converting
Sweden Inovyn Converting

Source: EuroChlor

One outlier remains: The Swedish Chemical Agency has permitted Inovyn to continue operating a mercury-cell chlorine plant in Stenungsund, Sweden, until the second quarter of 2018 to give the firm time to complete a conversion.

Mercury and most of its compounds are highly toxic. Vapors can be inhaled, and mercury can be absorbed via the skin. In 2016 European chlorine producers released a total of 1.4 metric tons of mercury into the atmosphere. At the end of 2016 they were still using about 5,400 metric tons of mercury in the cells that electrolyze sodium chloride into chlorine and sodium hydroxide.

In 2001 the European chlorine industry proposed to voluntarily stop producing chlorine using mercury by 2020. EU regulators decided that this was not soon enough and set the phaseout date. In the U.S., where no equivalent regulation exists, only one plant still uses mercury.

Six of the 21 mercury cell plants are located in Spain, with the rest spread across the bloc.

Hydrochem Italia shut down its mercury cell chlorine plant just yesterday with the loss of 30 jobs, according to the Italian newspaper La Stampa. The firm plans to convert its plant and reinstate staff when the facility reopens at the end of 2019.

Spain’s Elnosa closed its mercury process plant in Lourizán just before the deadline. The firm is seeking to convert the facility to make chlorine bleach using a new technology. However, jobs at the plant are now under threat because the local government won’t allow Elnosa to continue using the site, the firm says.

A major clean-up of mercury-based hazardous waste is now set to take place at the 21 sites. EU regulations allow for liquid mercury to be stored temporarily for up to five years with a possible extension of three years. Liquid mercury must be converted to mercury sulfide before its permanent disposal.

“Issues such as the demolition of buildings and the treatment and follow-up of contaminated sites will continue to keep the chlor-alkali industry busy for several more years,” EuroChlor says.

 
Chemical & Engineering News
ISSN 0009-2347
Copyright © American Chemical Society

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